Reason is that Assimp custom material attribute names are also prefixed
with $ and other weird characters, which could lead to them appearing
before $LayerName, causing a layer to falsely appear unnamed. A space,
instead, is before all printable characters so it's guaranteed to be
always first.
Some things you just don't realize at first. Fortunately the binary
layout isn't pinned yet for the serialization format so this change is
mostly fine.
Vladimír Vondruš